Bullion mixtures in silver coinage from ancient Greece and Egypt

Journal article


Albarède, Francis, Davis, Gillan, Gentelli, Liesel, Blichert-Toft, Janne, Gitler, Haim, Pinto, Marine and Telouk, Philippe. (2024). Bullion mixtures in silver coinage from ancient Greece and Egypt. Journal of Archaeological Science. 162, pp. 1-8. https://doi.org/10.1016/j.jas.2023.105918
AuthorsAlbarède, Francis, Davis, Gillan, Gentelli, Liesel, Blichert-Toft, Janne, Gitler, Haim, Pinto, Marine and Telouk, Philippe
Abstract

Was silver coinage minted from fresh metal newly extracted from the mine or was it from recycled silver deriving from older coins, silverware, or cult objects? The answer helps understand the provenance of coins and their circulation. Using Pb isotopes, the present work proposes a method to disentangle the sources of 368 silver-alloy coins from Athens, Corinth, Aegina, Thasos, Thrace, Macedonia, and Ptolemaic Egypt. We outline a new mixing model based on Principal Component Analysis and allowing for multiple steps of bullion recycling. The first component accounts for 94–99% (typically 97–99%) of the total variance, which indicates that the data form a well-defined alignment indicative of a nearly binary mixture between two source ores referred to as ‘end-members’. Isotopic evidence establishes the subordinate but pervasive practice of remelting. The strong skewness of the first principal component distribution shows that lead is dominated by the binary mixing of end-members. The geologically young end-member has high 206Pb/204Pb and is best exemplified by Laurion ore used in Athenian coinage. With the possible exception of Ptolemaic samples, the second end-member attests to the persistence of a low-206Pb/204Pb, geologically much older, end-member. In most cases, the distributions of a further two principal components are nearly symmetric and can be considered normal. If they represent ore sources, their very small contribution to the total variance qualifies them as ‘noise’ (caused by random isotopic fluctuations in the ores and analytical issues). We find that the Pb isotope ratios in the coinage issued by each minting authority are distributed as a power law. The slope of this distribution varies from one mint to another, with the steepest slopes (Corinth and Ptolemaic Egypt) indicating the predominance of freshly mined silver. The shallow slope of Macedonia demands a larger proportion of geologically old Pb. Silver supplied to the mint of Athens shifted from a mixture of high- and low-206Pb/204Pb in the late 6th c. BCE to a predominance of unmixed high-206Pb/204Pb ore from the mines of Laurion thereafter and fell back to a mixture with intermediate Pb isotope compositions in the second half of the 4th c. BCE. The limitation of the present study resides in the relatively small number of Pb isotope data for each mint, which, in most cases, prevents a statistically significant analysis of these data by periods. Nevertheless, the quasi-binary nature of most silver mixes stands out as a new and strong first-order, albeit somewhat counterintuitive, inference from the present data.

KeywordsPb isotopes; Silver coinage; Greece ; Mixing ; Recycling
Year01 Jan 2024
JournalJournal of Archaeological Science
Journal citation162, pp. 1-8
PublisherAcademic Press (Elsevier)
ISSN0305-4403
Digital Object Identifier (DOI)https://doi.org/10.1016/j.jas.2023.105918
Web address (URL)https://www.sciencedirect.com/science/article/pii/S030544032300198X?via%3Dihub
Open accessOpen access
Research or scholarlyResearch
Page range1-8
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License
File Access Level
Open
Output statusPublished
Publication dates
Online23 Dec 2023
Publication process dates
Accepted11 Dec 2023
Deposited09 Jul 2024
Additional information

© 2024 The Authors. Published by Elsevier Ltd

This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).

Place of publicationUnited Kingdom
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